synthetic inorganic chemistry for energy and catalysis
Saouma Group
At the U: ( undergrad authors in green ) in preparation: 32. C.    T.    Saouma.     “DEI    discussion    in    undergraduate    inorganic    chemistry    enhances    equity    and inclusivity.” 31. C.    L.    Mathis,    L.   A.    Gilbert ,   A.    Larkin ,    G.    C.    Perea ,    and    C.    T.    Saouma .    “Different    Effects    of Temperature on the Effective Hydricity of Two (De)hydrogenation Catalysts 30. S.   Kurup,   K.   Schlenker,   R.   T.   VanderLinden   and   C.   T.   Saouma .   “Effect   of   sterics   and   metal   on   the mechanism of CO 2  hydrogenation to formate” published: 29.  K.   Schlenker,   L.   K.   Casselman ,   R.   T.   VanderLinden,   C.   T.   Saouma .   C atal.   Sci.   Technol .,   2023 ,   13 , 1358-1368.   “Large   Changes   in   Hydricity   as   a   Function   of   Charge   and   Not   Metal   in   (PNP)M-H (De)hydrogenation Catalysts That Undergo Metal-Ligand Cooperativity.” ( link ) 28. A.   T.   Cannon ,   C.   T.   Saouma .   Polyhedron ,   2021 ,   207 ,   115375.      “Ru   catalyzed   hydrogenation   of   CO 2   to    formate    under    basic    an d    acidic    conditions.”    ( link )    Undergraduate    Research    In    Inorganic Chemistry 2021 Special Issue 27. K.   Schlenker,   E.   G.   Christensen,   A.   A.   Zhanserkeev,   G.   R.   McDonald,   E.   L.   Yang ,   K.   T.   Lutz,   R.   P. Steele,   R.   T.   VanderLinden,   C.   T.   Saouma .   ACS   Catal .,   2021 ,   11 ,   8358-8369.   “Role   of   Ligand- Bound CO 2  in the H ydrogenation of CO 2  to Formate with a (PNP)Mn Catalyst.”( link ) 26. F.   Wang,   A.   T.   Cannon ,   M.   Bhattacharya,   R.   Baumgarten,   R.   T.   VanderLinden,   C.   T.   Saouma . Chem   Commun. ,   2020 ,   56 ,   12142-12145.   “Hydrogenation   and   electrocatalytic   reduction   of   carbon dioxide to forma te with a single Co catalyst.” ( link ) Chem Commun. 2020 Emerging Investigators 25.  M.   Bhattacharya,   S.   Sepghati ,   R.   T.   VanderLinden,   C.   T.   Saouma .   J.   Am.   Chem.   Soc .,   2021 ,   142 , 41,   17589-17597.   “Toward   Combined   Catbon   Capture   and   Recycling:   Addition   of   an   Amine   Alters Product   Selectivity   fro m   CO   to   Formic   Acid   in   Manganese   Catalyzed   Reduction   of   CO 2 .”   ( link ) Selected to be part of the JACS Early Career Investigators Virtual Issue 24. M.   Bhattacharya,   K.   J.   Chandler ,   J.   Geary ,   C.   T.   Saouma .   Dalton   Trans .,   2020 ,   49 ,   4751-4757. “The   role   of   leached   Zr   in   the   photocatalytic   reduction   of   CO 2    to   formate   by   UiO-66   metal   organic frameworks.” ( lin k ) 23.  M.    Bhattacharya,    S.    Sebghati ,   Y.    M.    Vercella ,    C.    T.    Saouma .    Journal    of    the    Electrochemical Society ,   2020 ,   167 ,   086507.      “Electrochemical   Reduction   of   Carbamates   and   Carbamic   Acids: Implications for Combined Carbon Capture and Electrochemical CO 2 Recycling.” ( link ) 22. C.    L.    Mathis,    C.    T.    Saouma .    Polyhedron,    2020 ,    179 ,    114377.    “Protic    Media    Enhanced Protodebor onation for a Potential H 2 O 2 Sensing MRI Contrast Agent.” ( link ) 21. T.   Elkin,   C.   T.   Saouma * .   “Photoreduction   and   cascade   reactions   of   nitroaromatics   by   Uio-66-Hf   and Uio-66-Zr metal organic  frameworks.” Inorganica Chimica Acta , 2019  ( link )   20. C. L. Mathis, J. Geary, Y. Ardon, M. S. Reese, M. A. Philliber, R. T. VanderLinden, and C. T. Saouma*. J. Am. Chem. Soc., 2019, 141, 14317 - 14328. “Thermodynamic Analysis of Metal- Ligand Cooperativity of PNP Ru Complexes: Implications for CO2 Hydrogenation to Methanol and Catalyst Inhibition.” (link) Pre University of Utah: 19. T.   Zerk,   C.   T.   Saouma ,   J.   M.   Mayer * ,   and   W.   B.   Tolman * ,   Inorg.   Chem.,   2019 ,   58 ,   14151   -   14158. “Low    Reorganization    Energy    for    Electron    Self-Exchange    by    a    Formally    Copper(III,II)    Redox Couple.” 18. C.   T.   Saouma ,   C.-C.   Tsou,   S.   Richard,   R.   Ameloot,   F.   Vermoortele,   S.   Smolders,   B.   Bueken,   A.   G. DiPasquale,   W.   Kaminsky,   C.   N.   Valdez,   D.   E.   De   Vos * ,   and   J.   M.   Mayer * ,   Chem.   Sci .,   2019 ,   10 , 1322   –   1331.   “Sodium-coupled   electron   transfer   reactivity   of   metal-organic   frameworks   containing titanium clusters: the importance of cations in redox chemistry.” 17. C.   T.   Saouma * ,   S.   Richard,   S.   Smolders,   M.   F.   Delley,   R.   Ameloot,   F.   Vermoortele,   D.   E.   De   Vos * , and   J.   M.   Mayer * ,   J.   Am.   Chem.   Soc .,   2018 ,   140 ,   16184   –   16189.   “Bulk-to-surface   proton-coupled electron transfer reactivity in the metal-organic framework MIL-125.” 16. C.   T.   Saouma * ,   W.   D.   Morris,   J.   W.   Darcy,   and   J.   M.   Mayer * ,    Chem.   Eur.   J. ,    2015 ,    21 ,   9256   -   9260. “Protonation and Proton-Coupled Electron Transfer at S-Ligated [4Fe-4S] Clusters.” 15. A. Albers,   S.   Demeshko,   S.   Dechert,   C.   T.   Saouma ,   J.   M.   Mayer,   and   F.   Meyer,   J. Am.   Chem.   Soc., 2014 ,   136 ,   3946   -   3954.   “Fast   Proton-Coupled   Electron   Transfer   Observed   for   a   High   Fidelity Structural and Functional [2Fe-2S] Rieske Model.” 14. C.   T.   Saouma ,   Margaux   M.   Pinney,   and   J.   M.   Mayer,   Inorg.   Chem.,   2014 ,   53 ,   3153   -   3161.   “Electron Transfer   and   Proton-Coupled   Electron Transfer   Reactivity   and   Self-Exchange   of   Synthetic [2Fe-2S] Complexes: Models for Rieske and mitoNEET Clusters.” 13. C.   T.   Saouma   and   J.   M.   Mayer,   Chem.   Sci. ,   2014 ,   5 ,   21   -   31.   “Do   Spin   State   and   Spin   density Affect Hydrogen Atom Transfer Reactivity?” 12. C.   T.   Saouma ,   C.   C.   Lu,   M.   W.   Day,   and   J.   C.   Peters,   Chem.   Sci. ,   2013 ,   4 ,   4042   -   4051.   “CO 2   reduction by Fe(I): solvent control of C-O cleavage versu s C-C coupling.” 11. C.   A.   Laskowski,   G.   R.   Morello,   C.   T.   Saouma ,   T.   R.   Cundari,   and   G.   L.   Hillhouse,   Chem.   Sci. , 2013 ,   4 ,   170   -   174.   “Single-Electron   Oxidation   of   N -Heterocyclic   Carbene-Supported   Nickel Amides Yielding Benzylic C-H Activation.” 10. C.   T.   Saouma ,   C.   C.   Lu,   and   J.   C.   Peters,   Inorg.   Chem.,   2012 ,   51 ,   10043   –   10054.   “Mononuclear Five- and Six-Coordinate Iron Hydrazido and Hydrazine Species.” 9. C.   T.   Saouma ,   W.   Kaminsky,   and   J.   M.   Mayer,   Polyhedron ,   2013 ,   58 ,   60   –   64.   “Decomposition   of   a Mixed-Valence [2Fe-2S] Cluster to Linear Tetra-Ferric and Ferrous Clusters.” Invited contribution to the Michelle Millar special issue. 8. R.   A.   Kinney,   C.   T.   Saouma ,   J.   C.   Peters,   and   B.   M.   Hoffman,   J.   Am.   Chem.   Soc. ,   2012 ,   134 , 12637   –   12647.   “Modeling   the   Signatures   of   Hydrides   in   Metalloenzymes:   ENDOR Analysis   of   a   Di- iron Fe(μ–NH)(μ–H)Fe Core.” 7. C.   T.   Saouma ,   W.   Kaminsky,   and   J.   M.   Mayer,   J.   Am.   Chem.   Soc. ,   2012 ,   134 ,   7293   –   7296. “Protonation   and   Concerted   Proton–Electron   Transfer   Reactivity   of   a   Bis-Benzimidazolate   Ligated [2Fe–2S] Model for Rieske Clusters.” 6. C.   T.   Saouma ,   C.   E.   Moore,   A.   L.   Rheingold,   and   J.   C.   Peters,   Inorg.   Chem. ,   2011 ,   50 ,   11285   11287.   “A   Five–Coordinate   Phosphino/Acetate   Iron(II)   Scaffold   That   Binds   N 2 ,   N 2 H 2 ,   N 2 H 4 ,   and   NH 3   in the Sixth Site.”   5. C.   T.   Saouma ,   and   J.   C.   Peters,   Coord.   Chem.   Rev. ,   2011 ,   255 ,   920   –   937.   “M≡E   and   M=E Complexes of Iron and Cobalt that Emphasize Three-Fold Symmetry (E = O, N, NR).” Invited contribution to the “A Celebration of Harry B. Gray's 75th Birthday” issue. 4. C.   T.   Saouma ,   R.   A.   Kinney,   B.   M.   Hoffman,   and   J.   C.   Peters,   Angew.   Chem.   Int.   Ed. ,   2011 ,   50 , 3446    –    3449.    “Transformation    of    an    [Fe(η 2 –N 2 H 3 )] +     Species    to    π–Delocalized    [Fe 2 (μ–N 2 H 2 )] 2+/+   Complexes.” Featured as an SSRL Science Highlight (Dec. 2011). 3. C.   T.   Saouma ,   P.   Müller,   and   J.   C.   Peters,   J.   Am.   Chem.   Soc.,   2009,   131,   10358   –   10359. “Characterization of Structurally Unusual Diiron NxHy Complexes.” 2. J.–U.   Rhode,   T. A.   Betley,   T. A.   Jackson,   C.   T.   Saouma ,   J.   C.   Peters,   and   L.   Que   Jr.,   Inorg.   Chem. , 2007 ,   46 ,   5720   –   5726.   “XAS   Characterization   of   a   Nitridoiron(IV)   Complex   with   a   Very   Short   Fe−N Bond.” 1. C.   C.   Lu,   C.   T.   Saouma ,   M.   W.   Day,   and   J.   C.   Peters,   J. Am.   Chem.   Soc. ,   2007 ,   129 ,   4   –   5.   “Fe(I)- Mediated Reductive Cleavage and Coupling of CO 2 : An Fe II (μ–O,μ–CO)Fe II  Core.”
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